Chemistry-soaps And Detergents :: essays research papers

Cleaning with soap and soapless detergents. Detergent comes from the Latin word detergere meaning to clean, it is delimitate as a cleansing agent. thitherfore, water system itself is a detergent. This essay looks at soap and soapless (or synthetic) detergents. Both substances we use everyday and have a better-looking market commercially, they effect everyone. Soaps are make from natural products and soapless detergents are produced chemically, from each one having advantages and disadvantages.Soap has a ofttimes longer history than its relatively new synthetic version. There is evidence of soap made in Mediterranean countries around 2500 years ago. The basic process has not changed much although now the chemistry is understood. Soap is made from the process called saponification, the alkaline hydrolysis of fats and oils. It is basically the reverse of esterification. O OR-C-O-R + NaOH ---- R-C-O-Na+ + ROHEster(fat) + base(caustic pappa) ---- salt of fatty acid(soap) + alcohol (glycerol). deadly potash ( super C hydroxide) can be utilise instead of caustic soda (sodium hydroxide)but is more expensive. The base used to come from wood ash containing potassium carbonate which formed potash as this was not plentiful it made soap a luxury. The cheapest source of the ester is animal and vegetable fats and oils. H-H-H-H-H-H-H-H-H-H-H-H-H-H-H OH-C-C-C-C-C-C-C-C-C-C-C-C-C-C-C-C-CH-H-H-H-H-H-H-H-H-H-H-H-H-H-H O-Na+This is an example of a soap molecule. The hydrocarbon block off is non polar and hydrophilic (water hating) and the carboxylate end is polar and hydrophilic (water loving). This the property which allows it to clean, it acts as an emulsifying agent. The soap disperses in water to form miscelles where a negatively charged surface is formed and hydrocarbon manacles are in the centre. These miscelles surround droplets of dirt or grease suspending them in the water so they can be washed away. In haywire neutral water soap works very well. However in ha rd water those containing ions (calcium and magnesium ions) the soap reacts with the ions forming insoluble salts, scum which settles on fabrics and around the bath. A scum is also the result when soap is used in acidic water. Soap is also affected by the reputation of the dirt, for example perspiration breaks down the soap reducing the washing power. There are other disadvantages of soap, it deteriorates on storage lacks cleaning power and doesnt rinse out completely. The production of synthetic detergents are an example of a standard chemical approach. If a useful substance has some hateful properties an attempt is made to make a near copy synthetically which will perform better.